 |
|
 |
Material Safety Data Sheet
POP
Section 1
| CHEMICAL PRODUCT AND COMPANY IDENTIFICATION |
| MSDS Name |
: |
4-(Tert.-Octyl) Phenol, 99% |
| Synonyms |
: |
Para Octyl Phenol,
POP,
PTOP |
Company Identification
(India) |
: |
NAIKNAVARE CHEMICALS LIMITED
21-Keluskar Road, 1,Vidyabhavan,
Shivaji Park, Dadar - (W), Mumbai - 400 028. |
For information in India,
Call |
: |
022-444 0621 / 444 0615
022-444 9150 /446 8608. |
Section 2
| COMPOSITION, INFORMATION ON INGREDIENTS |
| CAS # |
: |
140-66-9 |
| Chemical Name |
: |
4-(Tert-Octyl) Phenol |
| % |
: |
99% |
| Hazard Symbols |
: |
XN |
| Risk Phrases |
: |
36/37/38 42/43 |
Section 3
| HAZARD IDENTIFICATION |
| EMERGENCY OVERVIEW |
| Appearance |
: |
White to Off-White |
| Warning ! |
: |
Hygroscopic. Causes eye and skin irritation. Causes digestive & respiratory tract irritation. May cause sensitization by inhalation and by skin contact. |
| Target Organs |
: |
Respiratory system, skin. |
| POTENTIAL HEALTH EFFECTS |
| Eye |
: |
Causes severe eye irritation. |
| Skin |
: |
Causes skin irritation. May cause skin sensitization, an allergic reaction,which becomes evident upon re-exposure to this material. |
| Ingestion |
: |
May cause gastrointestinal irritation with nausea, vomiting and diarrhea. |
| Inhalation |
: |
Causes digestive & respiratory tract irritation. May cause sensitization by inhalation and exposure may result in inflammation of the mucous membranes and in eczematous eruptions |
| Chronic |
: |
Repeated or prolonged exposure may cause allergic reactions in sensitive individuals. |
Section 4
| FIRST AID MEASURES |
| Eyes |
: |
Get medical aid immediately. Immediately flush eyes with plenty of Water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Do not allow victim to rub or keep eyes closed. |
| Skin |
: |
Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. |
| Ingestion |
: |
Never give anything by mouth to an unconscious person. Get medical aid. Do not induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water. |
| Inhalation |
: |
Remove from exposure to fresh air immediately. If breathing is difficult, give Oxygen. Get medical aid. Do not use mouth-to-mouth respiration. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask. |
| Notes to Physicians |
: |
Treat symptomatically and supportively. |
| Antidote |
: |
None reported |
Section 5
| FIRE FIGHTING MEASURES |
| General Information |
: |
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. |
| Extinguishing Media |
: |
Use water spray to cool fire-exposed containers. Do not get water inside containers. For small fires, use dry chemicals, carbon dioxide, or water spray. For large fires, use dry chemicals, carbon dioxide, alcohol-resistant foam, or water spray. |
Section 6
| ACCIDENTAL RELEASE MEASURES |
| General Information |
: |
Use proper personal protective equipment as indicated in Section 8. |
| Spills/Leaks |
: |
Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, observing precautions in the Protective Equipment Section. Avoid generating dusty conditions. Provide ventilation. Do not get Water inside containers. |
Section 7
| HANDLING AND STORAGE |
| Handling |
: |
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Do not allow contact with water. Keep from contact with moist air and steam. |
| Storage |
: |
Store in a tightly closed container. Store in cool, dry, well- ventilated area from incompatible substances. Store protected from moisture. |
Section 8
| EXPOSURE CONTROLS, PERSONAL PROTECTION |
| Engineering Controls |
: |
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentration low. |
| Exposure Limits |
| Chemical Name |
: |
4-(Tert-Octyl)phenol |
| ACGIH |
: |
None listed |
| NIOSH |
: |
None listed |
| NIOSH OSHA-Final PELs |
: |
None listed |
| OSHA Vacated PELs |
: |
No OSHA Vacated PELs are listed for this chemical. |
| Personal Protective Equipment |
| Eyes |
: |
Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. |
| Skin |
: |
Wear appropriate protective gloves and clothing to prevent skin exposure. |
| Clothing |
: |
Wear appropriate protective clothing to minimize contact with skin. |
| Respirators |
: |
Follow the OSHA respirator regulation found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary. |
Section 9
| PHYSICAL AND CHEMICAL PROPERTIES |
| Physical State |
: |
Flakes |
| Appearance |
: |
White to Off-White |
| Odor |
: |
None reported |
| PH |
: |
Not available |
| Boiling Point |
: |
263 °C @ 760.00mmHg |
| Melting Point |
: |
82 °C |
| Flash Point |
: |
132 °C |
| Reactivity: |
: |
0 |
| Explosion Limits |
:
: |
Lower : Not available
Upper : Not available |
| Decomposition Temperature |
: |
Not available |
| Specific Gravity/Density |
: |
0.940 g/cm3 |
| Molecular Formula |
: |
C14H220 |
| Molecular Weight |
: |
206.3 |
Section 10
| STABILITY AND REACTIVITY |
| Chemical Stability |
: |
Stable at room temperature in closed containers under normal storage and handling conditions. |
| Conditions to avoid |
: |
Incompatible materials, dust generation, excess heat, strong oxidants. |
| Incompatibilities with Other Materials |
: |
Oxidizing agents, bases, acid chlorides, brass, copper, copper alloys, steel, acid anhydrides. |
| Hazardous Decomposition Products |
: |
Carbon monoxide, carbon dioxide |
| Hazardous Polymerization |
: |
Has not been reported |
Section 11
| TOXICOLOGICAL INFORMATION |
| RTECS# |
: |
SJ8925000 |
| CAS# |
: |
140-66-9 |
| LD50/LC50 |
: |
CAS# 140-66-9 : Oral |
| |
|
Rat : LD50 = 2951 mg/kg. |
| |
|
Skin, Rabbit : LD50=2288 mg/Kg. |
| Carcinogenicity |
: |
Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA. |
| Epidemiology |
: |
Oral, Hampster: TDLo=252 gm/Kg/W-C (Tumorigenic-neoplastic by RTECS criteria Gastrointestinal-tumors) |
| Teratogenicity |
: |
No information available |
| Reproductive Effects |
: |
No information available |
| Neurotoxicity |
: |
No information available |
| Mutagenicity |
: |
No information available |
| Other Studies |
: |
Standard Draize test : Administration onto the skin (Rabbit)=500 mg/24H (mild)
Standard Draize test : Administration onto the eyes (Rabbit)=50mg/24H (severe) |
Section 12
| ECOLOGICAL INFORMATION |
| Ecotoxicity |
| Fish |
: |
Fathead minnow : LC50=5.1mg/L ; 96 Hr; Unspecified water Flea |
| Daphnia |
: |
EC50=4.2mg/L ; 24Hr; Unspecified Bacteria; Phytobacterium |
| Phosphoreum |
: |
EC50=0.21mg/L ; 5 Minutes; microtox test |
Section 13
| DISPOSAL CONSIDERATIONS |
Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste.
US EPA guidelines for the classification determination are listed in 40 CFR Part Additionally, waste generators must consult state and local hazardous waste regulation to ensure complete and accurate classification.
RCRA P-Series : None listed.
RCRA U-Series : None listed. |
Section 14
| TRANSPORT INFORMATION |
| US DOT |
| Shipping Name |
: |
TOXIC SOLIDS, ORGANICS, N.O.S. |
| Hazard Class |
: |
6.1 |
| UN Number |
: |
UN 2811 |
| Packing Group |
: |
III |
| Canadian TDG |
| Shipping Name |
: |
POISONOUS SOLIDS NOS |
| Hazard Class |
: |
6.1 (9.2) |
| UN Number |
: |
UN 2811 |
Section 15
| REGULATORY INFORMATION |
| US FEDERAL |
| TSCA |
| |
: |
CAS# 140-66-9 is listed on the TSCA inventory |
| Health & Safety Reporting List |
: |
None of the chemicals are on the Health & Safety Reporting List |
| Chemicals Test Rules |
: |
None of the chemicals in this product are under a Chemical Test Rule |
| Section 12b |
: |
None of the chemicas are listed under TSCA section 12b |
| TSCA Significant New Use Rule |
: |
None of the chemicals in this material have a SNUR under TSCA |
| SARA |
| Section 302 (RQ) |
: |
None of the chemicals in this material have an RQ |
| Section 302 (TPQ) |
: |
None of the chemicals in this products have a TPQ |
| Section 313 |
: |
No chemicals are reportable under Section 313 |
| Clean Air Act |
:
:
: |
This material does not contain any hazardous air pollutants
This material does not contain any Class 1 Ozone depletors
This material does not contain any Class 2 Ozone depletors |
| Clean Water Act |
: |
None of the chemicals in this product are listed as Hazardous Substances under the CWA |
| |
: |
None of the chemicals in this product are listed as Priority pollutant under the CWA |
| |
: |
None of the chemicals in this product are listed as a Toxic Pollutants under the CWA. |
| OSHA |
: |
None of the chemicals in this product are considered highly hazardous by OSHA |
| State |
: |
4-(Tert-Octyl)Phenol is not present on state list from CA, PA, MN, MA, FL or NJ California. No significant risk level. |
| |
: |
None of the Chemicals in this product are listed. |
| European/International Regulations |
| |
: |
European Labeling in Accordance with EC Directives |
| Hazard Symbols |
: |
XN |
| Risk Phrases |
: |
R 36/37/38 Irritating to eyes, respiratory system and skin |
| |
|
R 42/43 may cause sensitization by inhalation and skin contact. |
| Safety Phrases |
: |
S 22 Do not breath dust
S 24 Avoid contact to skin
S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
S 28 A after contact with skin, wash immediately with plenty of water
S 36/37/39 wear suitable protective clothings, gloves and eye/face protection
S 37 wear suitable gloves
S 45 In case of accident or if you feel unwell, seek medical advice immediately. |
| WGK (Water Danger/Protection) |
: |
2 |
| Canada |
| |
:
:
: |
CAS# 140-66-9 is listed on Canada's DSL/NDSL List
This product has a WHMIS classification of D2B
CAS# 140-66-9 is not listed on Canada's Ingredient Disclosure List |
| Occupational Exposure Limits |
| OEL-AUSTRALIA |
: |
TDA 10 ppm (60 mg/m3); STEL 20 ppm (120 mg/m3) |
| OEL-AUSTRIA |
: |
TWA 0.08 ppm (0.5 mg/ m3); Skin |
| OEL-DENMARK |
: |
TWA 0.08 ppm (0.5mg/m3); Skin |
| OEL-GERMANY |
: |
TWA 0.08 ppm (0.5 mg/m3); Skin |
| OEL-SWITZERLAND |
: |
TWA0.08 ppm (0,5 mg/m3); STEL 0.4 ppm; Skin |
Section 16
| ADDITIONAL INFORMATION |
| MSDS Creation Date : 21/03/2001 |
Revision Date : 02/12/2002 |
| The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no way shall the company be liable for
any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if the company has been advised of the possibility of such damages. |
Back To Top
|
|
 |
|
 |
|
